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Tables of Contents for Chemistry of Arsenic, Antimony and Bismuth
Chapter/Section Title
Page #
Page Count
List of contributors
x
Preface
xi
Arsenic, antimony and bismuth: some general properties and aspects of periodicity
1
38
C.J. Carmalt
N.C. Norman
Some general characteristics of the group 15 elements
1
15
Physical properties of the elements
1
10
Occurrence of the elements
11
2
Structures of the elements
13
3
Some general characteristics of group 15 element compounds
16
23
Stability of oxidation states
16
3
Covalent bond energies
19
2
Multiple bonds
21
2
Trends in acidity and basicity
23
6
Structural trends
29
6
Relativistic effects
35
1
Thermodynamic stability of the halides
36
1
References
37
2
Metallurgy of the elements
39
28
I.J. Polmear
Early history
39
3
Arsenic
39
2
Antimony
41
1
Bismuth
41
1
Occurrence
42
1
Extraction and refining
43
5
Arsenic
43
2
Antimony
45
1
Bismuth
46
2
Characteristics and physical properties
48
4
Uses of the elements
52
15
Antimonial lead
52
2
Fusible alloys
54
1
Solders
55
1
Bearing alloys
56
3
Semiconductors
59
1
Superconductors
60
1
Superplasticity
61
1
Sundry applications
62
1
Minor alloying additions
62
1
Acknowledgement
63
1
References
63
4
Inorganic derivatives of the elements
67
92
S.M. Godfrey
C.A. McAuliffe
A.G. Mackie
R.G. Pritchard
Introduction
67
1
The hydrides of arsenic, antimony and bismuth
67
19
Arsenic-hydrogen compounds
67
14
Antimony-hydrogen compounds
81
3
Bismuth-hydrogen compounds
84
2
The halides of arsenic, antimony and bismuth
86
14
Low valent transient halogen pnictogen species
86
1
Low valent stable halogen pnictogen species
86
1
Tervalent arsenic, antimony and bismuth halides
87
9
Pentavalent pnictogen halides
96
4
The binary pnictogen chalcogen compounds
100
17
Oxides of the pnictogens
101
7
Sulphides of the pnictogens
108
7
Selenides of the pnictogens
115
2
Tellurides of the pnictogens
117
1
Oxoanion compounds
117
27
Oxoanion derivatives of the pnictogen(III) acids
118
6
Oxoanion derivatives of the pnictogen(V) acids
124
20
Pnictogen intermetallic compounds
144
15
s-Block intermetallics of the pnictogens
144
3
p-Block intermetallics of the pnictogens
147
1
d-Block intermetallics of the pnictogens
147
1
f-Block intermetallics of the pnictogens
148
1
Pnictogen alloys
149
3
References
152
7
Coordination chemistry and solution chemistry
159
48
S.M. Godfrey
C.A. McAuliffe
A.G. Mackie
R.G. Pritchard
Arsenic, antimony and bismuth compounds as Lewis bases
159
3
Halogenoanion complexes of the pnictogens
162
17
Tervalent halopnictogen complex anions
162
15
Pentavalent halopnictogen complex anions
177
2
Complexes containing group 15 donor ligands
179
4
Arsenic(V) complexes
179
1
Antimony(V) complexes
180
1
Arsenic(III) complexes
180
1
Antimony(III) complexes
180
2
Bismuth(III) complexes
182
1
Complexes containing group 16 donor ligands
183
7
Arsenic(V) complexes
184
1
Antimony(V) complexes
184
1
Arsenic(III) complexes
184
1
Antimony(III) complexes
185
1
Bismuth(III) complexes
186
4
The aqueous chemistry of the pnictogens
190
17
The aqueous chemistry of tervalent pnictogen compounds
191
4
The aqueous chemistry of pentavalent pnictogen compounds
195
4
References
199
8
Organoarsenic and organoantimony compounds: synthesis, properties and uses in organic transformations
207
76
W.I. Cross
S.M. Godfrey
C.A. McAuliffe
A.G. Mackie
R.G. Pritchard
Introduction: synthesis of organoarsenic and organoantimony compounds
207
1
The synthesis of tervalent organoarsenic and organoantimony compounds
207
46
Precursors
208
4
Primary and secondary arsines and stibines
212
1
Tertiary arsines and stibines
212
8
Organobis(arsines) and bis(stibines), R(ER'2)2
220
9
Multidentate arsine and stibine ligands
229
6
Cyclic organoarsenic and organoantimony compounds
235
18
Pentavalent organoarsenic compounds
253
14
Low-coordinate pentavalent organoarsenic compounds
253
1
Four-coordinate pentavalent organoarsenic compounds
254
9
Five-coordinate pentavalent organoarsenic compounds
263
2
Five-coordinate pentavalent organoarsenic compounds
265
2
Six-coordinate pentavalent organoarsenic compounds
267
1
Some uses of organoarsenic and antimony compounds in organic synthesis
267
5
Arsenic ylides and related compounds
267
2
Anchored arsenic and arsenic-containing polymers
269
1
Antimony-Wittig and allied reactions
270
1
The uses of dihalogen arsoranes and stiboranes
271
1
Multiple bonds in organoarsenic compounds
272
11
One-coordinate organoarsenic compounds
272
1
Compounds with arsenic-arsenic double bonds
273
1
Compounds with arsenic-carbon double bonds
274
2
References
276
7
Organobismuth compounds: synthesis, properties and uses in organic transformations
283
62
H. Suzuki
Y. Matano
Introduction
283
1
Organobismuth(III) compounds
284
23
Triorganylbismuth(III) compounds
284
9
Organobismuth(III) compounds with bismuth-halogen bonds
293
6
Organobismuth(III) compounds with bismuth-chalcogen bonds
299
3
Organobismuth(III) compounds with bismuth-nitrogen bonds
302
1
Organobismuth(III) compounds with bismuth-bismuth bonds
303
2
Organobismuth(III) compounds with bismuth-metal/metalloid bonds
305
2
Organobismuth(V) compounds
307
21
Triorganylbismuth(V) compounds
307
5
Oxybis [triorganylbismuth(V)] compounds
312
2
Tetraorganylbismuth(V) compounds
314
5
Penta- and hexaorganylbismuth(V) compounds
319
3
Bismuthonium ylides
322
3
Bismuthine imides
325
1
Bismuthine oxides
326
2
Bismuthinic acids and esters
328
1
Bismuth-containing heterocycles
328
17
Bismacycles
328
4
Heterobismacycles
332
5
References
337
8
Organotransition metal compounds with element to transition metal bonds
345
122
K.H. Whitmire
Introduction
345
1
Metal complexes with ER3 ligands
345
1
EMx Complexes
346
57
Electron precise molecules
Hypervalent compounds
`Electron deficient' species: arsinidene, stibinidene and bismuthinidene complexes
Electron precise EMx complexes with one or more M-M bonds
Complexes with encapsulated E atoms
346
57
Metal complexes with fragments containing E-E bonds
Complexes with E2 fragments
Complexes with E3 fragments
Complexes with Ex fragments (x ≥ 4)
Concluding comments and future directions
References
Environmental and medicinal chemistry of arsenic, antimony, and bismuth
J. Reglinski
Introduction
Group 15 in the environment
Toxicology
The medicinal chemistry of group 15
Sleeping sickness, melarsoprol and arsenic
Leishmaniasis and antimony
Helicobacter pylori, bismuth and the eradication of ulcers
New therapies
Group 15 in the human circulatory system
Stress and inducable proteins
Immuno-chemistry and radiochemistry
Staining
References
403
38
Analytical methods
H. Onishi
Arsenic
Decomposition or digestion of samples
Separations
Methods of determination
Speciation
Analysis of arsenic, gallium arsenide and arsine
Antimony
Decomposition or digestion of samples
Separations
Methods of determination
Speciation
Analysis of antimony and antimony(III) oxide
Bismuth
Decomposition or digestion of samples
Separations
Methods of determination
Analysis of bismuth and bismuth(III) oxide
References
441
26
Index
467