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Tables of Contents for Physical Chemistry of Non-Aqueous Solutions of Cellulose and Its Derivative
Chapter/Section Title
Page #
Page Count
Series Preface
ix
Preface
xi
Introduction
1
2
Phase Equilibria and Liquid Crystalline Order in Solutions of Cellulose and Its Derivatives
3
34
Prediction of polymer solubility and formation of lyotropic liquid crystals in solutions of celluose and its derivatives
3
26
Thermotropic mesomorphism of cellulose derivatives
29
8
References
33
4
Influence of the Solvent on the Equilibrium and Kinetic Rigidity of the Molecular Chain of Cellulose and Its Derivatives in Solution
37
28
Modelling of the conformational characteristics of macromolecules of cellulose and its derivatives
38
2
Hydrodynamic and conformational parameters of cellulose and its derivatives in non-aqueous solutions
40
8
Influence of the molecular characteristics of cellulose and its derivatives on equilibrium rigidity in solution
48
7
Regularities in the influence of mixed solvents on the conformational parameters and phase transitions of cellulose derivatives
55
4
Influence of dielectric properties of solvents on the equilibrium rigidity of molecules of cellulose derivatives in solution
59
6
References
61
4
Thermochemistry of Dissolution of Cellulose in Non-aqueous Solvents
65
34
Enthalpic characteristics of solvation of non-electrolytes
65
3
Mathematical models for calculation of the excess enthalpy of mixing
68
2
Enthalpies of solution, dilution and mixing of polysaccharides: dextrans in water, non-aqueous and mixed solvents
70
3
Influence of solvent nature on the enthalpy of interaction with cellulose and its derivatives
73
3
Influence of the degree of substitution of hydroxyl groups of cellulose macromolecules by esteric groups and of the physico-chemical properties of solvents on the solution enthalpies of cellulose
76
10
Influence of the degree of substitution of hydroxy groups of cellulose macromolecules by acetate groups and of polymer concentration on the enthalpies of solution of polyethylene glycol in solutions of cellulose acetates in dimethyl sulfoxide
86
1
Chemical heterogeneity and thermochemical properties of cellulose
87
1
Relation between the structure of cellulose and its derivatives and the thermochemical characteristics of dissolution
87
5
Dependence of the enthalpies of solution, dilution and interaction on the molecular mass of polymers
92
7
References
93
6
Solvation of Cellulose and Its Derivatives in Non-aqueous Solutions
99
12
The use of nuclear magnetic relaxation of molecular probes to estimate the formation of H-complexes in non-aqueous solutions of cellulose derivatives
100
10
IR spectroscopy of non-aqueous solutions of cellulose
110
1
References
110
1
Mathematical Models of Cellulose and Its Derivatives in Solution
111
48
Dilute solutions
112
30
Methodological questions
112
6
Equilibrium properties
118
4
Dynamic properties
122
5
Moderately dilute solutions. Scaling and computer simulation
127
3
Monodisperse systems; concentration dependences
130
8
Polydisperse systems
138
1
Polymer liquids. Conformational structure of macromolecules
139
3
Correlation in liquid polymers
142
2
Reptation motion
144
2
Partially ordered systems. Liquid-crystalline polymers
146
4
Equilibrium properties
146
3
Dynamic properties
149
1
Dynamics of the conformational rearrangements of cellulose
150
9
References
153
6
Rheological Behaviour of Lyotropic LC Systems Based on Cellulose and Its Derivatives
159
32
Rheological properties of non-aqueous solutions of cellulose, its ethers and esters
159
7
Influence of polymer concentration on the conformational state of macromolecules in solution and on the rheological characteristics
166
2
Influence of shear deformation on the rheological properties and conformational parameters of concentrated solutions of rigid-chain polymers
168
2
Peculiarities of the rheological behaviour of lyotropic LC systems based on cellulose and its derivatives
170
21
References
187
4
Index
191