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Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1, 3-butadiene
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Bibliographic Detail
Publisher Springer Verlag
Publication date March 9, 2017
Binding Hardcover
Book category Adult Non-Fiction
ISBN-13 9789811007729
ISBN-10 9811007721
Original list price $119.00
Other format details sci/tech
Summaries and Reviews
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This thesis offers novel methods for catalyst and process design for the selective hydrogenation of acetylene and 1,3-butadiene. The author predicts the properties of supported Pd–Ni bimetallic catalysts using density functional theory (DFT) calculations and temperature-programmed desorption (TPD). The excellent correlation between model surfaces and supported catalysts demonstrates the feasibility of designing effective bimetallic catalysts for selective hydrogenation reactions. The author also proposes a method for designing non-precious metal catalysts to replace precious metals. She modifies the process of selective hydrogenation of acetylene by coupling the selective adsorption to the selective hydrogenation in the liquid phase, as a result of which the ethylene selectivity is greatly improved and heat transfer is greatly enhanced. Lastly, by analyzing the mechanism of liquid-phase hydrogenation, the author proposes a multi-stage slurry bed reactor for industrial applications.<



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Hardcover
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from Springer Verlag (March 9, 2017)
9789811007729 | details & prices | List price $119.00
About: This thesis offers novel methods for catalyst and process design for the selective hydrogenation of acetylene and 1,3-butadiene.

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