search for books and compare prices
Tables of Contents for Technetium
Chapter/Section Title
Page #
Page Count
A. Chemistry
1
371
Introduction
3
1
Discovery
4
2
References
5
1
Natural occurrence
6
4
Primordial technetium
6
1
Non-primordial technetium
7
1
Technetium in stars
8
1
References
8
2
Artificial occurrence
10
25
Technetium in the nuclear fuel cycle
11
4
Technetium in the environment
15
17
Retention in soils, sediments, and rocks
15
3
Occurrence in rainwater, freshwater, and the atmosphere
18
1
Accumulation in plants, microorganisms, and animals
19
7
Occurrence in the marine environment
26
5
Conclusion
31
1
References
32
3
Isotopes and isomers
35
8
Production and isolation of 99Tc
36
3
Nuclear properties of 99Tc
39
1
Laboratory handling of technetium nuclides
40
1
References
41
2
Some fundamentals of technetium chemistry
43
12
Electrochemistry
44
3
Thermodynamic data
47
2
Stability and reactivity of technetium compounds
49
3
References
52
3
Analytical chemistry
55
32
Determination methods
55
11
Radiometry
55
3
Spectrometry
58
2
Spectrophotometry
60
2
Gravimetry
62
1
Electrochemical methods
63
1
Polarography
63
2
Stripping voltammetry
65
1
Titration techniques
65
1
Separation methods
66
17
Volatilization
66
1
Solvent extraction
67
1
Pertechnetate
67
10
Complex compounds
77
2
Chromatography
79
1
Ion exchange chromatography
79
3
Adsorption chromatography
82
1
References
83
4
Uses of technetium-99
87
7
Radiation source
87
1
Catalyst
87
4
Technetium (VII) as an oxidizing agent
91
1
Pertechnetate as an inhibitor of corrosion
91
1
References
92
2
Technetium metal
94
10
Preparation
94
1
Physical properties
95
2
Chemical properties
97
1
Intermetallic compounds
97
3
Superconducting intermetallic compounds and alloys of technetium
100
1
References
101
3
Binary compounds and oxide halides
104
23
Hydrides
104
1
Borides
104
1
Carbide
105
1
Nitride
106
1
Phosphides
106
1
Arsenides
107
1
Oxides
107
5
Technetium dioxide
108
1
Ditechnetium pentaoxide and technetium trioxide
109
1
Ditechnetium heptaoxide
110
2
Sulphides
112
1
Technetium disulphide
112
1
Ditechnetium heptasulphide
112
1
Selenides and tellurides
113
1
Halides and oxide halides
113
11
Fluorides and oxide chlorides
114
6
Chlorides and oxide chlorides
120
2
Bromide, oxide bromides, and oxide iodide
122
2
References
124
3
Oxotechnetates
127
18
Pertechnetic acid
127
1
Salts of pertechnetic acid
128
8
Tetraoxotechnetate (VI)
136
3
Ternary and quaternary oxides
139
3
References
142
3
Complex chemistry of technetium-99
145
226
Technetium (VII)
145
7
Hydridotechnetate
145
1
(TcO3)+-core complexes
146
2
(TcN)4+-core complexes
148
1
Imido complexes
149
3
Technetium (VI)
152
10
Halogen containing complexes
152
1
Imido complexes
153
1
Nitrido complexes
154
6
Catecholato and thiolato complexes
160
2
Technetium (V)
162
82
Hexafluoro complexes
162
1
Diarsine, benzenethiolato, and thiocarbamato complexes
163
2
(TcO)3+-core complexes
165
1
Oxotetrahalogeno and oxopentahalogeno complexes
165
3
Oxocyano and oxothiocyanato complexes
168
1
TcO(O4)-, TcO(O2Cl)-, TcO(O2CL3)-, and TcO(O5)-core complexes
169
2
TcO(S4)-, TcO(OS3)-, TcO(O2S2)-, TcO(Se)4-, and TcO(S2Se2)-core complexes
171
4
TcO(N4)-, TcO(N4Cl)-, TcO(N3O)-, TcO (N3O2)-, TcO(N2O2)-, TcO(N2O2Cl)-, TcO(N2O3)-, and TcO(NO4)-core complexes
175
6
TcO(N2S2)-, TcO(N3S)-, and TcO(NS3)-core complexes
181
10
TcO(N3Cl2)-, TcO(N3Br2)-, TcO(N2Cl3)-, and TcO(N2Br3)-core complexes
191
1
TcO(N2O2Cl)-, TcO(N2O2Br)-, TcO(N2OCl2)-, TcO(N2OBr2)-, TcO(NOCl3)-, TcO(NOBr3)-, and TcO(NO2Cl)-core complexes
192
5
TcO(N2OS)-, TcO(N2OS2)-, TcO(NOS2)-, TcO(NO2S)-, TcO(N2S2Cl)-, TcO(NOSCl)-, and TcO(N2SCl)-core complexes
197
6
TcO(N2OP2)-, TcO(P2S2Cl)-, TcO(P2O2Cl)-, TcO(P2O3)-, and TcO(NP3Cl2)-core complexes
203
5
(TcS)3+-core complexes
208
1
TcS(S4)-and TcS(N3Cl2)-core complexes
208
1
Trans-(TcO2)+-core complexes
209
1
TcO2(N4)-core complexes
209
3
TcO2(N2S2)-, TcO2(NO3)-, TcO2(N2O2)-, and TcO2(NO2S)-core complexes
212
1
TcO2(P4)-, TcO2(P3)-, and TcO2(P2N2)-core complexes
212
2
Trans-dioxotetracyanotechnetate(V), [TcO2 (CN)4]3-
214
1
Dinuclear oxo complexes
215
1
μ-Oxo compounds
215
2
Other ligand-bridged compounds
217
3
(TcN)2+-core complexes
220
1
Nitridohalogeno-, nitridothiocyanato-, and nitridocyanotechnetate
220
2
TcN(O4)-, TcN(O2S2)-, TcN(S4)-,TcN(Se)4-, and TcN(S4Cl)-core complexes
222
4
TcN(N4)-, TcN(N4O)-, TcN(N4Cl)-, TcN (N4Br)-, and TcN(N3Br2)-core complexes
226
4
TcN(N2S2)-, TcN(N2P2Cl)-, TcN(N,S,O,P)-, TcN(NSO2)-, TcN(N,S,Cl,P)-, and TcN(NO2P)-core complexes
230
4
TcN(PS4)-, TcN(P2S2)-, TcN(P2Cl2)-, TcN (P2Br2)-, TcN(As2Cl2)-, TcN(As2Br2)-, TcN(P3Cl2)-, TcN(P3Br2)-, TcN(PCl3)-, TcN(PBr3)-, and TcN(P4Cl)-core complexes
234
5
Imido, hydrazido, diazenido, and diazene complexes
239
1
Imido complexes
239
3
Hydrazido, diazenido, and diazene complexes
242
2
Technetium(IV)
244
15
Hexahalogeno and hexathiocyanato complexes, nonabromoditechnetate(IV)
245
6
Tc(O)6-, Tc(O4Cl2)-, Tc(O4Br2)-, Tc(O2Cl4)-, {Tc(μ-O)(O2N2)}2-, {Tc(μ-O)(O3N)}2-, and {Tc(μ-O)O4}2-core complexes
251
3
{Tc(S4)}2-, Tc(S6)-, Tc(S8)-, Tc(SNCl4)-, Tc(N2Cl4)-, Tc(N2Br4)-, Tc(N4Cl2)-, and Tc(N3O3)-core complexes
254
2
Complexes containing phosphine ligands
256
3
Technetium (III)
259
39
Cyano, nitrile, isonitrile, and isothiocyanato complexes
259
2
Halogeno-phosphine and -arsine complexes
261
3
β-Diketonato- and carboxylato complexes
264
3
Complexes containing introgen heterocycles, dioximes, Schiff bases, diazenido groups, and other nitrogen ligands
267
8
Thiolato, phosphinethiolato, dithiocarbamato, thioureato, xanthato, and other complexes with sulphur containing ligands
275
11
Carbonyl and cyclopentadienyl complexes
286
2
Dinuclear μ-oxo-, μ-carboxylato-, μ-oxopyridinato-bridged complexes
288
4
Dinuclear complexes with multiple Tc-Tc bonds
292
2
Ternary chalcogenide clusters
294
4
Technetium (II)
298
17
Halogeno and isothiocyanato complexes with phosphine, phosphonite or arsine ligands
299
2
Oxalato, thiolato, thiocarbamato, and thioether complexes
301
2
Complexes containing nitrogen heterocycles
303
3
Complexes containing nitrosyl or thionitrosyl groups
306
3
Dinuclear and polynuclear complexes
309
6
Technetium (I)
315
33
Cyano and isonitrile complexes
315
4
Phosphine, phosphite, phosphonite, and phosphinite complexes
319
2
Complexes containing nitrogen ligands
321
2
Complexes containing nitrosyl or thionitrosyl ligands
323
4
Arene complexes
327
1
Compounds containing carbonyl ligands
328
20
Technetium (O)
348
4
Technetium(-I)
352
1
References
353
18
B. 99mTc Radiopharmaceutical Applications
371
54
Introduction
373
1
Generation of 99mTc
374
2
Imaging of organs
376
1
Synthesis aspects and requirements
377
2
Kits
379
1
Synthesis, structure and development
380
34
Brain perfusion imaging agents
380
1
[99mTcVO-d,l-HM-PAO]°
381
3
[99mTcVO-L,L-ECD]°
384
1
[99mTcIIICl(DMG)2MP]°
385
1
[99mTcVO(MRP-20)]°
385
1
[99mTcVO(NEP-DADT)]°
386
1
[99mTc(DTPA)]2-, [99mTcVO(glucoheptonate)2]-, and Na99mTcO4
387
1
Myocardial perfusion imaging agents
388
1
[99mTcI(MIBI)6]+
389
1
[99mTcIII(teboroxime)]°
390
1
[99mTcVO2(tetrofosmin)2]+
390
1
[99mTcIII(furifosmin)]+
391
1
[99mTc-pyrophosphate]
392
1
Thyroid imaging with Na99mTcO4
392
1
Lung imaging with 99mTc-MAA and [99mTc(DTPA)]2-
392
1
Hepatobiliary imaging agents
392
2
[99mTcIII(HIDA)2]-
394
1
[99mTc-PMT]
394
1
99mTc-sulphur colloid and 99mTc-albumin colloid
394
1
Renal imaging agents
395
1
[99mTcVO(MAG3)]-
395
1
[99mTc(DTPA)]2-
395
1
[99mTc-DMSA] and [99mTcVO(glucoheptonate)2]-
396
1
[99mTcVO-L,L-EC]2-
397
1
Bone imaging agents
397
3
99mTc-labeled red blood cells (99mTc-RBCs) and white blood cells (99mTc-WBCs)
400
1
Tumor imaging agents
401
1
[99mTcVO(DMSA)2]-
401
2
[99mTcI(MIBI)6]+, [99mTcVO2(tetrofosmin)2]+, and [99mTcVO-d,l-HM-PAO]°
403
1
99mTc-labeled monoclonal antibodies
403
3
Some future prospects
406
1
Brain
406
1
Myocardium
407
1
Hypoxic tissue
408
2
Receptor binding
410
2
Dopamine transporter
412
2
Summary of 99mTc radiopharmaceuticals
414
1
References
415
10
C. Acronyms and abbreviations
425
14
Index
439