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Tables of Contents for Inorganic Chemistry
Chapter/Section Title
Page #
Page Count
Greek Alphabet - Important Symbols: Table II-V
xxxiii
Introduction
1
2
Part A Fundamentals of Chemistry. Hydrogen
3
274
Elements and Compounds
5
13
Pure Substances
5
10
Homogeneous and Heterogeneous Systems
5
1
Separation of Heterogeneous Systems
5
1
Separation Based on Differences in Density
6
1
Separation Based on Differences in Particle Size
7
1
Separation of Homogeneous Systems
7
1
Separation by Physical Methods
8
1
Phase Separation by Temperature Change
8
1
Phase Separation by Solvents
9
1
Phase Separation by Chromatography
9
1
Separation by Chemical Methods
10
1
Separation of Air into its Components
11
1
Liquid Air
12
1
Preparation
12
1
Properties
13
1
Fractionation of Liquid Air
14
1
The Concepts of Element and Compound
15
3
Atoms and Molecules
18
34
Theory of Atoms and Molecules
18
10
Mass Ratios in Chemical Reactions; the Atom Concept
18
1
Experimental Observations
18
1
Law of Conservation of Mass
18
1
Stoichiometric Laws
19
3
Dalton's Atomic Hypothesis
22
1
Volume Ratios in Chemical Reactions; the Concept of Molecules
22
1
Experimental Observations
22
1
Avogadro's Molecular Hypothesis
23
3
Choice of a Reference Value for Relative Atomic and Molecular Masses
26
2
Determination of Atomic and Molecular Mass
28
16
Determination of Relative Molecular Masses
28
1
Gaseous Substances
28
1
Equation of State of Ideal Gases
29
3
Methods of Determining Molecular Masses
32
1
Dissolved Substances
33
1
States of Matter
33
1
Phase Diagrams
33
3
Equation of State for Dissolved Substances
36
1
Methods of Determining Molecular Mass
37
2
Determination of Relative Atomic Masses
39
1
Determination by Quantitative Analysis of Compounds
39
1
Determination of Atomic Masses from the Specific Heat Capacities of Compounds
40
1
Gases
40
2
Solids
42
1
Absolute Atomic and Molecular Masses
43
1
Chemical Reactions (Part 1)
44
8
Exchange of Matter in Chemical Reactions
44
1
Chemical Reaction Equations
44
1
Classification of Chemical Reactions
45
2
Energy Changes in Chemical Reactions
47
1
Total Energy Change
47
2
Conversion of Free and Bound Energy
49
3
The Periodic System of the Elements (Part 1) Comparative Summary of the Elements
52
8
Classification of the Elements into a Periodic System
53
3
The Complete Periodic System
55
1
Nomenclature of Chemical Elements
56
1
Comparative Summary of the Elements
56
4
Discovery of the Chemical Elements
56
1
Distribution of the Chemical Elements
57
2
Properties of the Chemical Elements
59
1
Atomic and Molecular Ions
60
19
Ion Theory
60
9
Electrolytic Dissociation; The Concept of Ions
60
1
Experimental Observations: Quantitative Relationships in Electrolytic Decomposition
60
1
Arrhenius Ion Hypothesis
61
1
Classification of Electrolytes
61
2
Strength of Electrolytes
63
1
Reactions of Electrolytes
63
2
Electrolytic Decomposition: The Concepts of Electron and Proton
65
1
Experimental Observations: Mass Ratios in Electrolytic Deposition of Substances
65
1
Stoney's Electron Hypothesis and Rutherford's Proton Hypothesis
66
3
Determination of Ionic Mass
69
6
Mass Spectroscopy
69
1
How a Mass Spectrometer Works
69
2
Applications of the Mass Spectrometer
71
1
Determination of Relative Ionic Masses; the Isotope Concept
72
1
Qualitative Studies
72
2
Quantitative Studies
74
1
Ionization and Dissociation Energies
75
4
Atomic Structure
79
30
The Shell Model of the Atom
79
16
Building Blocks of Matter: The Concept of Elementary Particles
79
4
The Atomic Nucleus
83
1
Principles of Structure
83
1
Nucleon States and Stability
84
2
Diameter and Density of the Atomic Nucleus
86
1
Electron Shells
86
1
Principles of Structure
86
3
Electron States and Stability
89
1
One-Electron States
89
5
Diameters of Atoms and Ions
94
1
Atomic Spectra
95
14
Photons, the Units of Light
95
4
Electronic Spectra
99
1
Optical Spectra
100
4
X-Ray Spectra
104
2
Photoelectron Spectra
106
3
Molecular Structure. The Chemical Bond, Part I
109
58
The Electronic Theory of Valency
109
44
First-order Compounds
110
1
The Ionic Bond
110
1
Ionic Valency
111
1
The Lattice Energy of Ionic Crystals
112
2
Structures of Some Ionic Crystals
114
4
Ionic radii
118
1
Formation of Mixed Crystals
119
2
Covalent Bonding
121
1
Atomic Valency
121
3
Bond Order and Bond Length (Atomic radii)
124
3
Molecular Shape and Bond Angle
127
2
Bond Energy
129
3
Bond Character Intermediate Between Ionic and Covalent. Dipole Moment and Electronegativity
132
3
The Metallic Bond
135
1
Metallic Valency, Metal Lattice Energy, Metal Atom Radii
136
1
The Structures of Metals
137
5
Alloys
142
1
Bonding Intermediate between Metallic, Covalent, or Ionic; Semimetals, Electron Semiconductors
143
1
Nomenclature of First-Order Inorganic Compounds
144
1
Higher-Order Compounds
145
1
Complex Formation at an Electron Donor
146
1
Complex Formation at an Electron Donor-Acceptor
147
1
Complex Formation at an Electron Acceptor
148
3
Nomenclature of Inorganic Higher-Order Compounds
151
1
The Equivalent
152
1
Molecular Spectra
153
7
Introduction
153
2
Colors of Chemical Substances
155
1
General
155
2
Special Topics
157
3
Molecular Symmetry
160
7
Symmetry Elements and Operations
161
1
Point Groups
162
5
Molecular Transformations. The Chemical Reaction, Part II
167
67
Chemical Equilibrium
167
30
Reaction Rate
167
1
The Foreward Reaction
167
2
The Back Reaction
169
3
The Overall Reaction
172
1
The Equilibrium State
173
1
Mass Action Law
173
3
Special Applications of the Mass Action Law
176
1
The Distribution Law
176
1
Electrolytic Dissociation
177
6
Attaining Equilibrium More Rapidly
183
1
Acceleration by Catalysts
183
2
Acceleration by Increased Temperature
185
1
Equilibrium Displacement
185
1
Qualitative Relationships
185
1
Le Chatelier's Principle
185
1
Consequences of Le Chatelier's Principle
185
3
Quantitative Applications
188
5
Heterogeneous Equilibria
193
1
Solid-Gas Systems
193
1
Solid-Liquid Systems
194
3
Oxidation and Reduction
197
20
A New Concept of Oxidation and Reduction
198
1
The Redox System
198
1
Oxidation States
199
2
The Electrochemical Potential Series
201
1
The Standard Potential
201
1
General
201
3
Standard Potentials in Acidic and Basic Solutions
204
3
Relative Strengths of Common Oxidizing and Reducing Agents
207
2
The Concentration Dependence of the Standard Potential
209
1
General
209
5
Electrolytic Decomposition
214
3
Acidity and Basicity
217
17
Derivation of New Concepts of Acidity and Basicity
217
1
Bronsted Acids and Bases
217
3
Lewis Acids and Bases
220
1
The Strength of Bronsted Acids and Bases
221
1
Protochemical Potential Series
221
3
The Dependence of Bronsted Acidity and Basicity on Concentration
224
1
General
224
3
Very Strong Acids and Superacids
227
2
Strength and Hard/Soft Character of Lewis Acids and Bases
229
5
Hydrogen and its Compounds
234
43
Natural Hydrogen
234
13
Occurrence
234
1
Preparation
235
1
From Water
235
4
From Hydrocarbons
239
1
Physical properties
240
1
Chemical Properties
241
4
Atomic hydrogen
245
2
Light, heavy and super-heavy hydrogen
247
3
Preparation
247
2
Properties
249
1
Ortho- and Parahydrogen
250
2
Hydrogen compounds
252
25
Systematics and Compositions
252
1
Stochiometry
253
2
Structure and bonding
255
1
Ionic hydrides
255
3
Metallic hydrogen compounds
258
1
Covalent hydrogen compounds
259
5
Preparation
264
1
By Hydrogenolysis
264
2
By protolysis
266
1
By hydridolysis
267
1
Physical properties
267
3
Chemical properties
270
1
Thermal properties
270
1
Acid/base properties
271
2
Redox behavior
273
1
Applications of Element Hydrides
274
3
Part B Main Group Elements
277
849
Main Group Elements The Periodic System (Part II), Comparative Overview
279
13
Electron Configuration of the Main Group Elements
279
2
Arrangement of the Main Group Elements in the Periodic System
281
1
Trends in Some Properties of Main Group Elements (Table III)
281
11
Metallic and Nonmetallic Character
282
2
Valency
284
1
General Reactivity
285
3
Periodicities within the Main Groups
288
4
Basic Molecular Chemistry
292
96
Structures of Molecules
292
10
The Shapes of Molecules
292
8
Isomerism in Molecules
300
2
Bonding Models. The Chemical Bond, Part III
302
38
Atomic Orbitals
302
1
The Hydrogen Atom
302
2
Probability Functions of the Hydrogen Electron
304
5
Wavefunctions for the Hydrogen Electron
309
2
Atoms with Several Electrons
311
3
Polyatomic Systems
314
1
Relativistic Effects
314
3
Molecular Orbitals
317
1
Diatomic Molecules
317
1
General
317
2
The Linear Combination of Atomic Orbitals to Give Molecular Orbitals
319
8
Polyatomic Molecules
327
4
Hybrid Orbitals
331
1
General
331
2
Structure of Molecules with Single Bonds
333
4
Structures of Molecules with Multiple Bonds
337
3
Reaction Mechanisms of Molecules (The Chemical Reaction, Part III)
340
34
The Rate of Chemical Reactions
340
1
Chemical Rate Laws
340
3
Rates of Chemical Reactions
343
1
Half-lives of Chemical Processes
343
2
The Time Scale of Physical and Chemical Processes
345
5
The Mechanism of Chemical Reactions
350
2
Isomerizations
352
2
Dissociation and Association
354
1
Dissociation and Recombination
354
2
Elimination and Addition
356
2
Substitution Reactions
358
1
Homolytic Substitution Reactions
359
1
General
359
1
Radical Chain Reactions
359
3
Heterolytic Substitution Reactions
362
1
Nucleophilic Substitution Reactions
363
3
Nucleophilic Substitutions at Tetrahedral and Pseudo-Tetrahedral Centers
366
5
Conservations of Orbital Symmetry
371
3
Stereochemistry of Molecules
374
14
Stereoisomerism
375
9
Enantiomerism
384
Molecules with a Single Center of Chirality
376
2
Molecules with More than One Chiral Center
378
3
Diastereomerism
381
1
Isomers with Diastereomeric Configurations
381
2
Isomers with Diastereomeric Conformations
383
1
Stereochemical Dynamics
384
1
Enantioselective Reactions
384
1
Stereochemistry of Chemical Reactions
385
Isomers with Diastereomeric Conformations
383
5
The Noble Gases
388
14
Occurrence
389
1
Production
390
1
Physical Properties
391
1
Chemical Properties
392
10
Noble Gas Halides and their Derivatives
393
5
Noble Gas Oxides and Fluoride Oxides
398
4
The Halogen Group
402
68
Free Halogens
402
22
Fluorine
402
3
Chlorine
405
1
Occurrence
405
1
Preparation
405
1
From Sodium Chloride
406
2
From Hydrogen Chloride (Hydrochloric Acid)
408
1
Physical Properties
409
1
Chemical Properties
410
3
Bromine
413
2
Iodine
415
1
Occurrence
415
1
Preparation
415
1
Physical Properties
416
2
Chemical Properties
418
5
Astatine
423
1
Hydrogen Compounds of the Halogens
424
9
Hydrogen Fluoride
424
4
Hydrogen Chloride
428
2
Hydrogen Bromide
430
2
Hydrogen Iodide
432
1
Compounds of the Halogens Among Themselves
433
6
Diatomic Interhalogens
433
2
Polyatomic Interhalogen Compounds
435
4
Oxygen Acids of the Halogens
439
16
Classification and Structure
439
2
Oxygen Acids of Fluorine
441
1
Oxygen Acids of Chlorine
442
1
Hypochlorous Acid, HClO
442
2
Chlorous Acid, HClO2
444
1
Chloric Acid, HClO3
445
2
Perchloric Acid, HClO4
447
2
Oxygen Acids of Bromine
449
2
Oxygen Acids of Iodine
451
4
Oxides and Fluoroxides of the Halogens
455
15
Systematics and Structures
455
2
Oxygen Compounds of Fluorine
457
2
Oxides of Chlorine
459
1
Dichlorine Oxide, Cl2O
459
1
Chlorine Dioxide, ClO2
459
3
Other Chlorine Oxides
462
2
Oxides of Bromine
464
1
Oxides of Iodine
465
1
Oxide Fluorides of Chlorine, Bromine, and Iodine
466
4
The Chalcogen Group
470
128
Oxygen
470
33
Dioxygen
470
1
Occurrence
470
1
Production
471
1
Physical Properties
472
1
Chemical Properties
472
4
Excited and Atomic Oxygen
476
1
Singlet Oxygen
476
2
Color of Oxygen
478
1
Atomic Oxygen
479
1
Ozone
480
1
Preparation
480
1
From Oxygen
480
2
From Oxygen Compounds
482
1
Physical Properties
482
1
Chemical Properties
482
1
The Atmosphere
483
1
Composition of the Atmosphere
484
1
The Ozone Cycle
485
1
Formation and Decay of Ozone in the Middle and Upper Atmosphere
486
1
Formation and Decomposition of Ozone in the Lower Atmosphere
487
1
Catalytic Decomposition of Ozone in the Atmosphere
488
1
Chemistry in the Atmosphere and Its Consequences for the Environment
489
1
Chemistry in the Atmosphere
490
3
Water and the Hydrosphere
493
1
Occurrence
493
1
Purification
493
2
Physical Properties
495
1
Chemical Properties
496
1
Hydrogen Paroxide and Other Hydrogen Oxides
496
1
Preparation of H2O2
497
1
Physical Properties of H2O2
498
1
Chemical Propergties of H2O2
499
3
Salts
502
1
Sulfur
503
70
Elemental Sulfur
503
1
Occurrence
503
1
Extraction
503
2
Physical Properties
505
1
Aggregate States of Sulfur
505
3
Allotropic Modifications of Sulfur
508
5
Chemical Properties
513
1
Elemental Sulfur
513
2
Sulfur in Compounds
515
3
Hydrogen Compounds of Sulfur
518
1
Hydrogen Sulfide (Sulfane), H2S
518
4
Hydrogen Polysulfides Polysulfanes), H2Sn
522
1
Halogen Compounds of Sulfur
523
2
Sulfur Fluorides
525
3
Sulfur Chlorides, Bromides and Iodides
528
2
Oxides of Sulfur
530
1
Sulfur dioxide, SO2
531
2
Sulfur Trioxide, SO3
533
3
Lower Sulfur Oxides
536
1
Oxygen Acids of Sulfur
537
1
Systematics, Composition and Structure
537
2
Sulfurous Acid, H2SO3, and Disulfurous Acid, H2S2O5
539
3
Sulfuric Acid H2SO4, and Disulfuric Acid H2S2O7
542
1
Production
542
4
Physical Properties
546
1
Chemical Properties
547
2
Halogen Derivatives
549
2
Lower Sulfur Acids: H2SO2 and H2S2O2
551
1
Dithionous Acid, H2S2O4 and Dithionic Acid, H2S2O6
552
2
Thiosulfuric acid, H2S2O3
554
1
Polysulfane Monosulfonic Acids, H2SnO3, and Polysulfane Disulfonic Acids Polythionic Acids) H2SnO6
555
3
Peroxomonosulfuric Acid, H2SO5, and Peroxodisulfuric Acid, H2S2O8
558
1
Nitrogen Compounds of sulfur
559
1
Sulfur nitrides
559
1
Tetrasulfur Tetranitride S4N4
559
4
Other Sulfur Nitrides
563
2
Sulfur Nitride Ions
565
1
Sulfur Nitride Cations
565
2
Sulfur Nitride Anions
567
1
Sulfur Nitride Halides and Oxides
568
1
Sulfur-Nitrogen-Halogen Compounds
568
4
Sulfur-Nitrogen-Oxygen Compounds
572
1
Selenium
573
14
Elemental selenium
573
1
Physical Properties
573
3
Chemical Properties
576
2
Compounds of Selenium
578
1
Hydrogen Compounds of Selenium
578
1
Halogen Compounds of Selenium
579
3
Oxygen Compounds of Selenium
582
2
Sulfur Compounds of Selenium
584
1
Interchalcogens
585
1
Other Selenium Compounds
586
1
Tellurium
587
6
Elemental Tellurium
587
2
Tellurium Compounds
589
1
Hydrogen Compounds of Tellurium
589
1
Halogen Compounds of Tellurium
589
3
Oxygen Compounds of Tellurium
592
1
Other Tellurium Compounds
593
1
Polonium
593
5
The Nitrogen Group
598
180
Nitrogen
598
79
Elemental Nitrogen
598
1
Occurrence
598
1
Production
598
1
Physical Properties
599
1
Chemical Properties
600
1
Nitrogen in Compounds
601
2
Hydrogen Compounds of Nitrogen
603
1
Systematics and Structure
603
2
Ammonia, NH3
605
1
Production
605
3
Physical Properties
608
1
Chemical Properties
609
4
Ammonium Salts
613
3
Inversion of Ammonia and Other Molecules
616
2
Hydrazine, N2H4
618
1
Preparation
618
1
Properties
619
3
Internal Rotation of Hydrazine and Other Molecules
622
2
Hydrazoic Acid, HN3
624
1
Production
624
1
Properties
624
2
Pseudoelements and Paraelements
626
1
Triazane, N3H5, Tetrazane, N4H6 and Triazene, N3H3
627
1
Nitrene, NH
628
1
Diimine, N2H2
628
4
Tetrazene, N4H4
632
2
Halogen Compounds of Nitrogen
634
1
Nitrogen Chlorides, Bromides and Iodides
635
6
Nitrogen Fluorides
641
3
Oxides of Nitrogen
644
1
Dinitrogen monoxide, N2O
645
1
Nitrogen Monoxide (Nitric Oxide), No, and Dinitrogen Dioxide, N2O2
646
5
Dinitrogen Trioxide, N2O3
651
1
Nitrogen Dioxide, NO2; Dinitrogen Tetroxide, N2O4
652
2
Higher Nitrogen Oxides
654
1
Oxygen Acids of Nitrogen
655
1
Fundamentals
655
2
Hydroxylamine, NH2OH
657
2
Hyponitrous acid, H2N2O2 and Hydrogen Oxonitrate (I) (Nitroxyl); HNO
659
2
Oxohyponitrous Acid, H2N2O3
661
1
Nitrous acid, HNO2
661
1
Preparation and Structure
661
1
Properties
662
2
Nitrosyl Compounds, Nitrosylation
664
4
Nitric Acid, HNO3
668
1
Preparation
668
1
Physical Properties
669
1
Chemical Properties
670
1
Salts
671
1
Nitryl compounds
672
3
Sulfur Compounds of Nitrogen
675
2
Phosphorus
677
64
Elemental Phosphorus
677
1
Occurrence
677
1
Preparation
678
2
Physical Properties
680
3
Chemical Properties
683
2
Phosphorus in Compounds
685
4
Hydrogen Compounds of Phosphorus
689
1
Systematics and Composition
689
4
Monophosphane, PH3
693
3
Acyclic Phosphanes
696
2
Monocyclic Phosphanes
698
1
Polycyclic Phosphanes
699
4
Halogen Compounds of Phosphorus
703
1
Phosphorus(III) Halides
704
2
Phosphorus(II) and Phosphorus(I) Halides
706
1
Phosphorus (V) Halides
706
2
Pseudorotation and Other Ligand Exchange Processes
708
1
Oxides of Phosphours
709
3
Oxygen Acids of Phosphorus
712
1
Systematics and Composition
712
4
Phosphonic Acid, H3PO2
716
1
Phosphonic Acid, H3PO3
717
2
Phosphoric acid, H3PO4
719
1
Physical Properties
719
1
Chemical Properties
720
1
Salts
721
3
Derivatives
724
3
Condensed Phosphoric Acids
727
1
Oligophosphoric Acids
728
2
Polyphosphoric Acids
730
1
Phosphates in Nature
731
1
Lower Phosphoric Acids
732
1
Peroxophosphoric Acids
733
1
Sulfur and Selenium Compounds of Phosphorus
733
3
Nitrogen Compounds of Phosphorus
736
1
Phosphorus Nitrides
736
1
Phosphazenes
737
3
Phosphazanes
740
1
Arsenic
741
16
Elemental Arsenic
741
3
Hydrogen Compounds of Arsenic
744
2
Halogen Compounds of Arsenic
746
2
Oxygen Compounds of Arsenic
748
5
Sulfur Compounds of Arsenic
753
2
Organic Compounds of Arsenic
755
2
Antimony
757
10
Elemental Antimony
757
2
Hydrogen Compounds of Antimony
759
1
Halogen Compounds of Antimony
760
3
Oxygen Compounds of Antimony
763
2
Sulfur Compounds of Antimony
765
1
Organic Compounds of Antimony
766
1
Bismuth
767
11
Elemental Bismuth
767
2
Compounds of Bismuth
769
9
The Carbon Group
778
151
Carbon
778
44
Elemental Carbon
778
1
Occurrence
778
2
Production, Physical Properties, and Structures
780
1
Graphite
780
5
Diamond
785
2
The Fullerenes
787
5
Chemical Properties
792
1
General Remarks
792
1
Graphite Compounds
793
2
Fullerene Compounds
795
2
Carbon in Compounds
797
2
Hydrogen Compounds of Carbon
799
1
Fundamentals
799
2
Properties
801
1
Organometallic Compounds
802
1
Halogen Compounds of Carbon
803
2
Oxygen Compounds of Carbon
805
1
Carbon Dioxide
805
4
Carbon Monoxide
809
5
Lasers and Their Applications
814
3
Sulfur Compounds of Carbon
817
2
Nitrogen Compounds of Carbon
819
3
Silicon
822
71
Elemental Silicon
822
1
Occurrence
822
1
Preparation
823
1
Physical Properties
824
1
Chemical Properties
825
1
Silicon in Compounds
826
1
Oxidation States and Coordination Numbers
826
1
Comparison of Silicon and Carbon
827
7
Silicon Ions, Silicides
834
1
Zint1 Phases
835
2
Hydrogen Compounds of Silicon
837
1
Fundamentals
837
2
Monosilane, SiH4
839
5
Higher Saturated Silanes
844
2
Silenes
846
2
Silylenes
848
1
Halogen Compounds of Silicon
849
1
Silicon (IV) Halides
849
3
Silicon (III) Halides
852
1
Silicon(II), Silicon(I), and Other Lower Silicon Halides
853
1
Oxides of Silicon
854
5
Other Binary Silicon Compounds
859
2
Oxygen Acids of Silicon. Silicates and Silicones
861
1
Fundamentals
861
4
Silicic Acids
865
1
Monosilicic Acid, H4SiO4
865
2
Polysilicic Acids
867
2
Colloidally-Dispersed Systems
869
1
Comparison of Coarse, Colloidal, and Molecular Dispersions
869
2
The Stability of Colloidal Solutions
871
1
Natural Silicates
872
1
Discrete, Dimeric, and Ring Silicates
873
1
Chain and Band Silicates (Inosilicates)
873
2
Layered Silicates (Phyllosilicates)
875
5
Lattice Silicates (Tectosilicates)
880
3
Industrial Silicates
883
1
Alkali Metal Silicates
883
1
Glasses
884
4
Pottery and Ceramic Objects
888
2
Silicones
890
3
Germanium
893
7
Elemental Germanium
893
3
Germanium (IV) Compounds
896
2
Germanium(II) Compounds
898
2
Tin
900
12
Elemental Tin
900
3
Tin(II) (Stannous) Compounds
903
1
Tin(II) Halides
903
1
Tin(II) Chalcogenides
904
2
Organic Tin(II) Compounds
906
1
Tin(IV) (Stannic) Compounds
907
1
Tin(IV) Hydride
907
1
Tin(IV) Halides
908
1
Tin(IV) Chalcogenides
908
2
Organic Tin(IV) Compounds
910
2
Lead
912
17
Elemental Lead
912
3
Lead(II) (Plumbous) Compounds
915
1
Lead(II) Halides
915
1
Lead(II) Chalcogenides and Lead(II) Salts
915
3
Organic Lead(II) Compounds
918
1
Lead(IV) (Plumbic) Compounds
918
1
Lead(IV) Hydrides and Halides
918
1
Lead(IV) Chalcogenides
919
2
Organic Lead(IV) Compounds
921
1
The Lead-Acid Storage Battery
921
8
The Boron Group
929
115
Boron
929
70
Elemental Boron
929
1
Occurrence
929
1
Preparation
930
1
Physical Properties
930
3
Chemical Properties
933
1
Boron in Compounds
933
3
Hydrogen Compounds of Boron
936
1
Classification and Bonding
936
7
Diborane, B2H6
943
1
Preparation
943
1
Properties
944
6
Monoboranates (Tetrahydroborates)
950
2
Higher Boranes
952
2
Tetraborane(10)
954
1
Pentaborane(9)
955
2
Decarborane(14)
957
2
Polyboranates (Hydridpolyboranates)
959
2
Heteroboranes
961
1
Systematics and Bonding
961
1
Carbaboranes
962
4
Other Non-metal Boranes
966
1
Metallaboranes (Boranate Complexes)
966
2
Halogen Compounds of Boron
968
1
Systematics and Bonding
968
2
Boron(III) Halides
970
3
Boron(II) Halides
973
1
Boron(I) Halides
974
1
Oxygen Compounds of Boron
974
1
Boron Oxides
975
1
Oxygen Acids of Boron
975
4
Borates
979
2
Sulfur Compounds of Boron
981
1
Nitrogen Compounds of Boron
982
1
Boron(II) Nitrides
983
1
Boron(III) Ammines, Amides and Imides
984
6
Lower-Valence Boron-Nitrogen Compounds
990
2
Phosphorus Compounds of Boron
992
2
Carbon Compounds of Boron. Organic Boron Compounds
994
1
Boron Carbides
994
1
Organic Derivatives of Monoborane
994
3
Organic Derivatives of Higher Boranes
997
1
Metal and Semimetal Compounds of Boron. Metal Borides
997
2
Aluminum
999
28
Elemental Aluminum
999
1
Occurrence
999
1
Production
1000
1
Production of Pure Aluminum Oxide from Bauxite
1000
1
Electrolysis of Fused Aluminum Oxide
1001
2
Physical Properties
1003
1
Chemical Properties
1003
2
Aluminum in Compounds
1005
2
Aluminum Hydrides
1007
4
Halogen Compounds of Aluminum
1011
3
Oxygen Compounds of Aluminum
1014
8
Other Binary Aluminum Compounds
1022
1
Organic Aluminum Compounds
1023
1
Aluminum Triorganyls and Their Derivatives
1023
4
Higher Aluminum Organyls (with Lower Valencies)
1027
1
Gallium, Indium and Thallium
1027
17
Elemental Gallium, Indium and Thallium
1027
1
Indium
1028
1
Thallium
1029
2
Trivalent Gallium, Indium and Thallium Compounds
1031
1
Hydrogen Compounds
1031
1
Halogen Compounds
1032
1
Chalcogen Compounds
1033
1
Pentele Compounds
1034
1
Organic Gallium(III), Indium(III) and Thallium(III) Compounds
1035
1
Lower Valency Gallium, Indium and Thallium Compounds
1036
1
Hydrogen Compounds
1036
1
Halogen Compounds
1036
1
Chalcogen Compounds
1037
1
Pentele Compounds
1038
1
Lower-Valency Organic Gallium, Indium and Thallium Compounds
1038
6
The Alkaline Earth Metal Group
1044
41
Beryllium
1044
9
Elemental Beryllium
1044
4
Compounds of Beryllium
1048
1
Inorganic Beryllium Compounds
1048
4
Organic Beryllium Compounds
1052
1
Magnesium
1053
10
Elemental Magnesium
1053
3
Compounds of Magnesium
1056
1
Inorganic Magnesium Compounds
1056
5
Organic Magnesium Compounds
1061
2
Calcium, Strontium, Barium and Radium
1063
22
Elemental Calcium, Strontium, Barium and Radium
1063
1
Occurrence
1063
2
Preparation
1065
1
Physical Properties
1065
1
Chemical Properties
1066
1
Alkaline Earth Metals in Compounds
1067
1
Compounds of Calcium, Strontium, Barium and Radium
1067
1
Hydrogen Compounds of Alkaline Earth Metals
1067
1
Halogen Compounds of the Alkaline Earth Metals
1068
2
Calcogen Compounds of the Alkaline Earth Metals
1070
2
Other Binary Alkaline Earth Compounds and Related Compounds
1072
1
Alkaline Earth Salts of Oxygen Acids
1073
5
Alkaline Earth Metal Complexes
1078
1
Organic Compounds of the Alkaline Earth Metals
1079
1
Mortars
1080
1
Air Mortars
1081
1
Hydraulic mortars
1082
3
The Alkali Metal Group
1085
41
Lithium
1085
9
Elemental Lithium
1085
2
Compounds of Lithium
1087
1
Inorganic Lithium Compounds
1087
2
Organic Lithium Compounds
1089
5
Sodium, Potassium, Rubidium, Cesium and Francium
1094
32
Elemental Sodium, Potassium, Rubidium, Cesium and Francium
1094
1
Occurrence
1094
2
Preparation
1096
1
Physical Properties
1097
2
Chemical Properties
1099
1
Alkali Metals in Compounds
1100
3
Compounds of Sodium, Potassium, Rubidium, Cesium and Francium
1103
1
Hydrogen Compounds of the Alkali Metals
1103
1
Halogen Compounds of the Alkali Metals
1104
3
Chalcogen Compounds
1107
4
Alkali Metal Salts of Oxygen Acids
1111
5
Complexes of the Alkali Metals
1116
4
Organic Compounds of the Alkali Metals
1120
6
Part C Transition Elements
1126
513
Transition Elements (Outer Transition Metals) The Periodic System of the Elements (Part III) and a Comparative Overview of the Transition Elements
1127
12
Electron Configurations of the Transition Elements
1127
3
The Position of the Transition Elements in the Periodic System
1130
2
Trends in Some Properties of the Transition Elements (Table IV)
1132
7
Similarities and Differences between Main Group and Transition Elements
1133
2
Periodicities within the Transition Groups
1135
4
Fundamentals of Complex Chemistry
1139
84
Structure and Stability of Transition Metal Complexes
1140
34
The Components of Complexes
1140
1
Ligands
1140
1
Monodentate Ligands
1140
3
Chelate Ligands
1143
2
Complex Centers
1145
1
Monatomic Metal Centers
1145
2
Metal Clusters
1147
4
The Stability of Complexes
1151
1
Formation Constants and Dissociation Constants of Complexes
1151
3
The Chelate Effect
1154
2
Redox Stability
1156
1
The Structure of Complexes
1157
10
Isomerism of Complexes
1167
1
Structural Isomerism of Complexes
1167
1
Stereoisomerism of Complexes
1168
4
Nomenclature of Complexes
1172
2
Bonding Models for Transition Metal Complexes (The Chemical Bond, Part III)
1174
30
Valence Bond Theory of Complexes
1174
1
Composition and Stability of Complexes
1174
4
Structure and Magnetic Properties of Complexes
1178
2
Ligand Field Theory of Complexes
1180
1
Energy-Level Splitting of the d Orbitals in the Ligand Field: Magnetic Behavior of Complexes
1181
7
Ligand Field Stabilization Energy: Stability and Structure of Complexes
1188
6
Splitting of Energy Sublevels in the Ligand Field: Optical Properties of Complexes
1194
1
Colors of Complexes
1194
1
d → d Transitions
1195
4
CT Transitions
1199
1
Molecular Orbital Theory of Complexes
1199
5
Reaction Mechanisms of Transition Metal Complexes (The Chemical Reaction, Part IV)
1204
19
Nucleophilic Substitution Reactions of Complexes
1204
1
Nucleophilic Substitution at Tetrahedral Centers
1205
1
Nucleophilic Substitution at Square Planar Centers
1205
3
Nucleophilic Substitution at Octahedral Centers
1208
6
Rearrangement Reactions in Complexes
1214
2
Redox Reactions of Complexes
1216
1
Electron-transfer Processes
1216
3
Redox Additions and Eliminations
1219
4
Some Fundamentals of Solid State Chemistry
1223
25
Melting and Freezing Diagrams of Binary Systems
1224
4
Precipitation of Pure Substances
1224
1
No Compound Formation
1224
2
Compound Formation
1226
1
Precipitation of Mixed Crystals
1227
1
Continuous Series of Mixtures - Complete Miscibility
1227
1
Presence of a Miscibility Gap
1228
1
Magnetic Properties of Solids (Magnetochemistry)
1228
10
Diamagnetism and Paramagnetism
1229
1
Material in a Magnetic Field. Magnetic Susceptibility
1229
1
Atomic Interpretation of Magnetic Susceptibility
1230
4
Ferromagnetism, Ferrimagnetism and Antiferromagnetism
1234
4
Electrical Properties of Solids
1238
10
Conductors, Nonconductors, Semiconductors
1238
1
Metals, Electronic Conductors
1238
2
Nonmetals. Electrical Nonconductors
1240
1
Semimetals. Electrical semiconductors
1240
2
Superconductors
1242
1
Conventional Superconductors
1243
2
High Temperature Superconductors
1245
3
The Copper Group
1248
43
Copper
1249
16
Elemental Copper
1249
1
Occurrence
1249
1
Preparation
1249
2
Physical Properties
1251
1
Chemical Properties
1252
1
Copper in Compounds
1253
1
Copper(I) Compounds (d10)
1253
5
Copper(I), Salts of Oxygen Acids
1258
1
Copper(II) Compounds (d9)
1259
5
Copper(III) and Copper(IV) Compounds (d8 and d7)
1264
1
Silver
1265
11
Elemental Silver
1265
1
Occurrence
1265
1
Preparation
1265
2
Physical Properties
1267
1
Chemical Properties
1267
1
Silver in Compounds
1268
1
Silver(I) Compounds (d10)
1269
3
Silver(II) Compounds (d9)
1272
1
Silver(III) and Silver(IV) Compounds (d8 and d7)
1273
1
The Photographic Process
1274
2
Gold
1276
12
Elemental Gold
1276
1
Occurrence
1276
1
Production
1277
1
Physical properties
1277
1
Chemical properties
1278
1
Gold in Compounds
1278
3
Gold(I) Compounds (d10) and Lower Valency Gold Compounds
1281
4
Gold(II) Compounds (d9)
1285
1
Gold(III) Compounds (d8)
1286
2
Gold(IV) and Gold(V) Compounds (d7, d6)
1288
1
Eka-Gold (Element 111)8
1288
3
The Zinc Group
1291
27
Zinc and Cadmium
1291
12
Elemental Zinc and Cadmium
1291
1
Occurrence
1291
1
Preparation
1292
2
Physical Properties
1294
1
Chemical Properties
1294
2
Zinc and Cadmium in Compounds
1296
1
Compounds of Zinc and Cadmium
1296
7
Mercury
1303
13
Elemental Mercury
1303
1
Occurrence
1303
1
Production
1303
1
Physical properties
1303
1
Physiological
1304
1
Chemical properties
1305
1
Mercury in Compounds
1305
2
Mercury(I) and Lower-valency Compounds
1307
3
Mercury(II) (Mercuric) Compounds (d10)
1310
6
Eka-Mercury
1316
2
The Scandium Group
1318
7
Elemental Scandium, Yttrium, Lanthanum and Actinium
1318
4
Preparation
1319
1
Physical Properties
1320
1
Chemical Properties
1320
1
Scandium, Yttrium, Lanthanum and Actinium in Compounds
1321
1
Compounds of Scandium, Yttrium, Lanthanum and Actinium
1322
3
The Titanium Group
1325
20
Titanium
1325
11
Elemental Titanium
1325
1
Occurrence
1325
1
Preparation
1326
1
Physical Properties
1327
1
Chemical Properties
1327
1
Titanium in Compounds
1328
1
Titanium(IV) Compounds (d10)
1329
4
Titanium(III) compounds d1)
1333
2
Titanium(II) compounds (d2)
1335
1
Zirconium and Hafnium
1336
6
Elemental Zirconium and Hafnium
1336
1
Occurrence
1336
1
Preparation
1337
1
Physical properties
1337
1
Chemical Properties
1337
1
Zirconium and Hafnium in Compounds
1338
1
Compounds of Zirconium and Hafnium
1339
3
Rutherfordium
1342
3
The Vanadium Group
1345
19
Vanadium
1345
10
Elemental Vanadium
1345
1
Occurrence
1345
1
Preparation
1345
1
Physical Properties
1346
1
Chemical Properties
1346
1
Vanadium in Compounds
1347
1
Vanadium(V) Compounds (d0)
1347
4
Vanadium(IV) Compounds (d1)
1351
2
Vanadium(III) and Vanadium(II) Compounds (d2, d3)
1353
2
Niobium and Tantalum
1355
7
Elemental Niobium and Tantalum
1355
1
Occurrence
1355
1
Preparation
1355
1
Physical Properties
1356
1
Chemical Properties
1356
1
Niobium and Tantalum in Compounds
1356
1
Compounds of Niobium and Tantalum
1357
1
Hydrogen and Related Compounds
1357
1
Halogen Compounds
1358
3
Cyano-Compounds
1361
1
Chalcogen Compounds
1361
1
Organic Niobium and Tantalum Compounds
1362
1
Hahnium (Eka-Tantalum)
1362
2
The Chromium Group
1364
41
Chromium
1364
18
Elemental Chromium
1364
1
Occurrence
1364
1
Preparation
1364
2
Physical Properties
1366
1
Chemical Properties
1367
1
Chromium in Compounds
1367
1
Chromium(VI) Compounds (d0)
1368
4
Chromium(V) and Chromium(IV) Compounds (d1, d2)
1372
2
Chromium(III) Compounds (d3)
1374
4
Chromium(II) Compounds (d4)
1378
4
Molybdenum and Tungsten
1382
20
Elemental Molybdenum and Tungsten
1382
1
Occurrence
1382
1
Preparation
1383
1
Physical Properties
1384
1
Chemical Properties
1384
1
Tungsten and Molybdenum in Compounds
1384
2
Molybdenum(VI) and Tungsten (VI) Compounds (d0)
1386
1
Hydrogen Compounds
1386
1
Halogen Compounds
1386
1
Oxygen Compounds
1386
8
Other Molybdenum(VI) and Tungsten(VI) Compounds
1394
1
Molybdenum(V, IV) and Tungsten(V, IV) Compounds (d1, d2)
1394
3
Molybdenum(III, II) and Tungsten(III, II) Compounds (d3, d4)
1397
5
Seaborgium
1402
3
The Manganese Group
1405
25
Manganese
1405
11
Elemental Manganese
1405
1
Occurrence
1405
1
Preparation
1406
1
Physical Properties
1406
1
Chemical Properties
1406
1
Manganese in Compounds
1407
1
Manganese(II) Compounds (d5)
1408
3
Manganese(III) and Manganese(IV) Compounds (d4, d3)
1411
2
Manganese(V), Manganese(VI) and Manganese(VII) Compounds (d2, d1, d0)
1413
3
Technetium and Rhenium
1416
12
Elemental Technetium and Rhenium
1416
1
Occurrence
1416
1
Preparation
1416
1
Physical Properties
1417
1
Chemical Properties
1417
2
Compounds of Technetium and Rhenium
1419
1
Hydrogen Compounds
1419
1
Halogen Compounds
1420
3
Cyano Compounds
1423
1
Oxygen Compounds
1423
2
Sulfur, Selenium and Nitrogen Compounds
1425
1
Technetium and Rhenium Complexes
1425
1
Organic Technetium and Rhenium Compounds
1426
2
Bohrium
1428
2
The Iron Group
1430
43
Iron
1430
28
Elemental Iron
1430
1
Occurrence
1430
1
Preparation
1431
1
Production of Pig Iron
1432
2
Steel Production
1434
2
Physical Properties
1436
2
Chemical Properties
1438
2
Iron in Compounds
1440
1
Iron(II) and Iron(III) Compounds (d6, d5)
1441
1
Hydrogen Compounds
1441
1
Halogen Compounds
1441
2
Cyano and Related Compounds
1443
3
Oxygen Compounds
1446
5
Other Fe(II) and Fe(III) Compounds
1451
2
Iron(III) and Iron(II) Complexes
1453
4
Organic Iron Compounds
1457
1
Iron(VI), Iron(V), and Iron(IV) Compounds (d2, d3, d4)
1457
1
Ruthenium and Osmium
1458
13
Elemental Ruthenium and Osmium
1458
1
Occurrence
1458
1
Preparation
1458
1
Physical Properties
1459
1
Chemical Properties
1459
1
Ruthenium and Osmium in Compounds
1459
1
Compounds of Ruthenium and Osmium
1460
1
Hydrogen Compounds
1460
1
Halogen Compounds
1461
3
Cyano Compounds
1464
1
Oxygen Compounds
1464
3
Ruthenium and Osmium Complexes
1467
4
Organic Ruthenium and Osmium Compounds
1471
1
Hassium
1471
2
The Cobalt Group
1473
27
Cobalt
1473
14
Elemental Cobalt
1473
1
Occurrence
1473
1
Preparation
1473
1
Physical Properties
1474
1
Chemical Properties
1474
1
Cobalt in Compounds
1474
1
Lower-valency Cobalt Compounds
1475
1
Cobalt(II) and Cobalt(III) Compounds (d7, d6)
1475
1
Hydrogen Compounds
1475
1
Halogen Compounds
1476
1
Cyano Compounds
1477
1
Oxygen Compounds
1478
3
Other Chalcogen Compounds
1481
1
Cobalt(II) and Cobalt(III) Complexes
1482
3
Organic Cobalt Compounds
1485
1
Cobalt(IV) and Cobalt(V) Compounds
1486
1
Rhodium and Iridium
1487
12
Elemental Rhodium and Iridium
1487
1
Occurrence
1487
1
Preparation
1487
1
Physical Properties
1487
1
Chemical Properties
1487
1
Rhodium and Iridium in Compounds
1488
1
Compounds of Rhodium and Iridium
1489
1
Hydrogen Compounds
1489
1
Halogen Compounds
1489
4
Cyano Compounds
1493
1
Oxygen Compounds
1493
2
Rhodium and Iridium Complexes
1495
1
Organic Rhodium and Iridium Compounds
1496
3
Meitnerium (Element 109)
1499
1
The Nickel Group
1500
30
Nickel
1500
11
Elemental Nickel
1500
1
Occurrence
1500
1
Preparation
1500
1
Physical Properties
1501
1
Chemical Properties
1501
1
Nickel in Compounds
1502
1
Nickel(II) and Nickel(III) Compounds (d8, d7)
1502
1
Hydrogen Compounds
1502
1
Halogen Compounds
1503
1
Cyano Compounds
1504
1
Oxygen Compounds
1505
1
Other Binary Nickel(II) Compounds
1506
1
Nickel(II) and Nickel(III) Complexes
1507
3
Organic Nickel Compounds
1510
1
Nickel(IV) Compounds (d6)
1511
1
Palladium and Platinum
1511
17
Elemental Palladium and Platinum
1511
1
Occurrence
1511
1
Preparation
1512
1
Physical Properties
1512
1
Chemical Properties
1513
1
Palladium and Platinum in Compounds
1513
1
Compounds of Palladium and Platinum
1514
1
Hydrogen Compounds
1514
1
Halogen Compounds
1515
5
Cyano Compounds
1520
1
Chalcogen Compounds
1520
3
Palladium and Platinum Complexes
1523
2
Organic Palladium and Platinum Compounds
1525
3
Eka-Platinum (Element 110)
1528
2
The Compounds of Transition Metals: A Comparative Review
1530
109
Some Classes of Inorganic Transition Metal Compounds
1530
21
Transition Metal Hydrides. σ-Complexes
1530
1
Monohydrogen Complexes
1531
2
Dihydrogen and Other σ-Complexes
1533
2
Transition Metal Halides. Halide-Type Metal Clusters
1535
1
Halides and Halogen Complexes
1536
1
Structure and Bonding
1536
3
Synthesis and Properties
1539
2
Halide-Type Metal-Cluster Complexes
1541
3
Transition Metal Oxides: Nonstoichiometry
1544
1
Oxides of the Transition Metals and Their Nonstoichiometric Behavior
1544
3
Dioxygen Complexes
1547
4
Some Classes of Organic Transition Metal Compounds
1551
88
Metal Carbonyls and Related Complexes
1552
1
Carbonyl-Type Metal Clusters
1552
1
The Metal Carbonyl
1552
7
Synthesis
1559
2
Properties
1561
5
Metal Carbonyl Anions, Hydrides and Cations
1566
1
Carbonyl Metallates
1566
5
Metal Carbonyl Hydrides
1571
4
Metal Carbonyl Cations
1575
1
Compounds Related to the Metal Carbonyls
1576
1
Thio-, Seleno- and Tellurocarbonyl Complexes
1576
1
Cyano Complexes
1577
2
Isocyanide (Isonitrile) Complexes
1579
3
Nitosyl Complexes
1582
9
Trifluorophosphane Complexes
1591
2
Other Organic n-Complexes of Transition Metals
1593
1
Metal Organyls
1593
5
Alkylidene (Carbene) Complexes
1598
1
Alkylidyne (Carbyne) Complexes
1599
1
Organic σ-Complexes of the Transition Metals
1600
1
Alkane Complexes
1601
2
π-Complexes with E-H and E-E Bonds
1603
1
Organic π-Complexes of Transition Metals
1604
1
Alkene (Olefin) Complexes
1604
1
Complexes with Ethylene and Its Derivatives
1604
4
Complexes with Butadiene and Its Derivatives
1608
2
Complexes with Allyl and Its Derivatives
1610
3
Alkyne (Acetylene) Complexes
1613
2
Aromatic Complexes
1615
1
Metallocenes and Their Derivatives. Homoleptic Cyclopentadienyl Metal Complexes
1616
7
Heteroleptic Cyclopentadienyl Metal Complexes
1623
4
Bis(benezene) Metal Complexes and Related Sandwich Compounds
1627
3
Mono(benzene) Metal Complexes and Related Half-Sandwich Compounds
1630
1
Other Aromatic Complexes
1631
2
Catalytic Processes Involving Metal Organyls
1633
6
Part D Lanthanides and Actinides
1639
105
The Periodic System of the Elements (Part IV): Lanthanides and Actinides - a Comparative Overview
1640
6
Electron Configurations of the Lanthanides and Actinides
1640
3
The Positions of the Lanthanides and Actinides in the Periodic System
1643
1
Trends in Some Properties of the Lanthanides and Actinides (Table IV)
1644
2
Fundamentals of Nuclear Chemistry
1646
47
Natural Transmutation of Elements
1646
19
Natural Radioactive Decay
1646
1
α- and β-- -Decay
1647
1
Displacement Rule
1647
1
Decay Series
1647
2
Natural Radionuclides
1649
1
Spontaneous and Cluster Decay
1650
1
Energy of Radioactive Decay
1651
1
Energy Content of Radioactivity
1651
1
Radiation Energy
1652
2
The Interaction of Radiation with Matter
1654
1
Uptake of Radiation Energy by Matter
1654
3
Radioactive Energy Conversion
1657
1
Mass Loss through Radiation
1657
1
Nuclear Binding Energy
1657
2
Radioactive Decay Rates
1659
1
Decay Constant, Half-life, Activity
1659
2
Radioactive Equilibrium
1661
2
Mechanism of Radioactive Decay
1663
2
Artificial Transmutation of Elements
1665
28
Single Nuclear Reactions
1666
3
Simple Nuclear Reactions
1669
1
Methods of Nuclear Transmutation
1669
1
Nuclear Transmutation with Helium Nuclei
1670
2
Nuclear Transmutations with Hydrogen Nuclei
1672
2
Nuclear Transmutations with Neutrons
1674
1
Nuclear Transmutations with Heavier Atomic Nuclei
1675
1
Nuclear Transmutation with γ-Rays
1676
1
Artificial Radioactivity
1676
3
Nuclear Fragmentation
1679
1
Nuclear Fission
1679
2
Nuclear Fusion
1681
4
The Nuclear Chain Reaction
1685
1
The Controlled Nuclear Chain Reaction
1686
4
The Uncontrolled Nuclear Chain Reaction
1690
3
The Lanthanides
1693
18
Occurrence
1694
2
Separation
1696
3
Physical Properties
1699
4
Chemical Properties
1703
2
Compounds of the Lanthanides
1705
6
Hydrogen Compounds
1705
1
Halogen Compounds
1705
2
Oxygen Compounds
1707
1
Compounds with Other Elements
1708
1
Complexes
1709
1
Metallo-Organic Compounds
1709
2
The Actinides
1711
33
Natural Actinide Nuclides
1712
1
Preparation of the Actinides
1713
5
Thorium
1713
1
Protactinium
1713
1
Uranium
1713
1
Transuranium Elements
1714
4
Physical Properties
1718
2
Chemical Properties
1720
7
Radiochemical Properties
1727
3
Compounds of the Actinides
1730
14
Hydrogen Compounds
1730
1
Halogen Compounds
1730
3
Oxygen Compounds
1733
2
Other Compounds
1735
1
Salts
1735
1
Complexes
1736
1
Organometallic Compounds
1737
2
Postscript: The Interconversion of Mass and Energy
1739
5
Part E Appendix
1744
27
I Numerical Tables
1745
3
Cosmic Data
1746
1
Conversion Factors: Energy &rlhar2; Mass &rlhar2; Electrical Potential &rlhar2; Wave-number
1746
1
Greek Numerical Prefixes
1747
1
II SI Units
1748
5
Basic SI Units
1748
1
Derived SI Units
1748
1
Prefixes Indicating Multiples and Fractions of a Unit
1749
1
Definitions of the Basic SI Units
1749
1
Definitions of Derived SI Units
1750
1
Conversion factors between SI and other commonly used units
1751
2
III Natural Nuclides
1753
3
IV Radii of Atoms and Ions
1756
4
V Bond Lengths (calc.) between Main-group Elements
1760
1
VI Standard Potentials
1761
4
VII Nobel Prizes for Chemistry and Physics
1765
6
Name Index
1771
6
Subject Index
1777